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Tert-Butyl peroxybenzoate TBPB CAS 614-45-9
Description
- CAS: 614-45-9
- Synonyms: Tert-Butyl peroxybenzoate,TBPB
- Einecs: 210-382-2
- Molecular Formula: C11H14O3
- Grade: 99.0%
- Package: 25kg/drum or as required
Details
Tert-Butyl peroxybenzoate TBPB CAS 614-45-9 is Yellowish, mobile liquid, consisting of technically pure tert.Butylperoxy benzoate. This aromatic perester is used as an initiator (radical source) in the polymerization of monomers, e.g. ethylene, styrene, methacrylates.
Specification:
Appearance | yellowish liquid |
Assay | 99.0% w/w min |
Peroxide content | ca. 99 % w/w |
Active oxygen | ca. 8.16 % w/w |
De-sensitising agent | None |
Density at 20°C | ca. 1.04 g/cm3 |
Viscosity at 20°C | ca. 8 mPa.s |
Refractive index at 20°C | ca. 1.499 |
Critical temperature (SADT) | ca. 60°C |
Cold storage stability | freezing point below ca. +10°C |
Recommended storage temperature | 10 to 40°C (104°F) |
Storage stability (activity) as from date of delivery | 6 months |
This product is in compliance with the ElektroG (EU-Directives: RoHS 2002/95/EG, WEEE 2002/96/EG)
Half-life Data :
10h/1h/1min (0.1 m / benzene): 104°C / 124°C / 165°C
Application:
ETHYLENE:
Initiator for the high pressure polymerisation of ethylene in combination with other peroxides of varying degrees of activity. Temperature range: 200-250°C. The product is liquid and readily miscible with high-boiling aliphatic hydrocarbons. At low temperatures and under high pressure, however, highlyconcentrated solutions can cause crystal precipitation in dosing pumps.
Disadvantage: formation of benzene as decomposition product, potential alternative could be tert.Butylperoxy-3,3,5-trimethylcyclohexane (TBPIN)
STYRENE:
Initiator for the polymerisation of styrene in bulk or suspension.
Temperature range: 100-140°C.
Usage level: 0.02-0.1% as supplied.
Particular advantages: reduction of residual monomer content in the polymer. We recommend the combination with more active peroxides, e.g. Dibenzoyl peroxide (BPO) or tert.Butylper-2-ethylhexanoate (TBPEH).
Disadvantage: formation of benzene as decomposition product, potential alternative could be tert.Butylperoxy-2-ethylhexylcarbonate (TBPEHC)
OTHER MONOMERS:
Initiator for the polymerisation of (meth)acrylates, and allyl monomers, where necessary in combination with more active peroxides, particularly Dibenzoyl peroxide or tert.Butylper-2-ethylhexanoate (TBPEH).
Temperature range: 100-140°C.
Usage level: 0.1-1% as supplied.
Package:
25kg in HDPE canister.
FAQ
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Q: What kinds of transportation types can you provide?A: We can provide a variety of transportation methods including sea transportation, air transportation, land transportation, express delivery, etc.
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Q: What is the minimum order quantity for the goods?A: A standard package is generally more convenient for transportation, but we can also repackage according to customer requirements.